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ChemInform Abstract: Stereoselective Phenylation of Allylic Alcohol Derivatives by Palladium-Catalyzed Cross-Coupling with Hypervalent Silicon Complexes.

✍ Scribed by M.-R. BRESCIA; P. DESHONG

Publisher: John Wiley and Sons
Year: 2010
Weight: 34 KB
Volume: 29
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199836099

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✦ Synopsis

Stereoselective Phenylation of Allylic Alcohol Derivatives by Palladium-Catalyzed Cross-Coupling with Hypervalent Silicon Complexes.

-The silicate complex (II) is found to be a highly effective reagent for the phenylation of allylic benzoates. The phenylation is completely stereoselective and occurs under mild conditions. In some cases excellent regioselectivity is also observed. -(

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