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ChemInform Abstract: Regio- and Stereoselective Direct Cross-Coupling of Aromatic Imines with Allenic Alcohols.

✍ Scribed by Martin McLaughlin; Heidi L. Shimp; Raul Navarro; Glenn C. Micalizio


Publisher
John Wiley and Sons
Year
2008
Weight
38 KB
Volume
39
Category
Article
ISSN
0931-7597

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Complex Allylation by the Direct Cross-C
✍ Masayuki Takahashi; Martin McLaughlin; Glennβ€…C. Micalizio πŸ“‚ Article πŸ“… 2009 πŸ› John Wiley and Sons 🌐 English βš– 408 KB πŸ‘ 2 views

## Abstract **Regioselective, stereoselective**: The convergent coupling of allylic alcohols with imines to deliver stereodefined homoallylic amines is described (see scheme). The process proceeds with net allylic transposition without the intermediacy of allylic organometallic reagents. Two stereo