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ChemInform Abstract: Base-Induced Chemiluminescent Decomposition of Stereoisomeric 5-tert-Butyl-1- (3-tert-butyldimethylsiloxy) phenyl-4,4-dimethyl-3-phenyl-2,6,7-trioxabicyclo[3.2.0]heptanes and Their Related Dioxetanes.

✍ Scribed by Masakatsu Matsumoto; Yoshihiro Ito; Jyunya Matsubara; Toshimitsu Sakuma; Yasuko Mizoguchi; Watanabe Nobuko Watanabe Nobuko

Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
32
Category
Article
ISSN
0931-7597

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## Thermal Decomposition of 1-(Aminophenyl)-5-tert-butyl-4,4dimethyl-2,6,7-trioxabicyclo [3.2.0]heptanes: Unusual O-O Bond Cleavage Competing with Normal Fragmentation of 1,2-Dioxetanes. -The dioxetanes (IIa)-(IIc) decompose thermally to give the normal carbonyl products (III) whereas compounds