ChemInform Abstract: Photoisomerization of 5,5-Dimethyl-3-(3,3-dimethylbut-1-ynyl)-2-(pent- 4-enyl)cyclohex-2-enone to tert-Butyl(4,4-dimethyl-2-oxotricyclo(7.3.0. 01,6)dodec-6-en-7-yl)carbene.
β Scribed by B. KISILOWSKI; W. C. AGOSTA; P. MARGARETHA
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 30 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0931-7597
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## Thermal Decomposition of 1-(Aminophenyl)-5-tert-butyl-4,4dimethyl-2,6,7-trioxabicyclo [3.2.0]heptanes: Unusual O-O Bond Cleavage Competing with Normal Fragmentation of 1,2-Dioxetanes. -The dioxetanes (IIa)-(IIc) decompose thermally to give the normal carbonyl products (III) whereas compounds