ChemInform Abstract: Synthesis of 5-(Adamantan-1-yl)-4,4-dimethyl-1-(3-oxyphenyl)-2,6,7-trioxabicyclo [3.2.0]heptanes and Their Base-Induced Chemiluminescent Decomposition in Liquid/Solid Phase.
✍ Scribed by Masakatsu Matsumoto; Masatoshi Tanimura; Masahiko Tachi; Nobuko Watanabe
- Publisher
- John Wiley and Sons
- Year
- 2008
- Weight
- 37 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0931-7597
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📜 SIMILAR VOLUMES
## Abstract Four bicyclic dioxetanes bearing a phenolic substituent, 3‐__tert__‐butyldimethylsiloxy‐4‐chlorophenyl (**3a**), 5‐__tert__‐butyldimethylsiloxy‐4‐chloro‐2‐ethylphenyl (**3b**), 5‐__tert__‐butyldimethylsiloxy‐2‐ethylphenyl (**3c**), and 3‐__tert__‐butyldimethylsiloxy‐4‐ethylphenyl (**3d*
## Thermal Decomposition of 1-(Aminophenyl)-5-tert-butyl-4,4dimethyl-2,6,7-trioxabicyclo [3.2.0]heptanes: Unusual O-O Bond Cleavage Competing with Normal Fragmentation of 1,2-Dioxetanes. -The dioxetanes (IIa)-(IIc) decompose thermally to give the normal carbonyl products (III) whereas compounds