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ChemInform Abstract: Asymmetric Reactions Catalyzed by Chiral Metal Complexes. Part 78. Chiral Thioimidazoline Ligands for Palladium-Catalyzed Asymmetric Allylation.

✍ Scribed by T. MORIMOTO; K. TACHIBANA; K. ACHIWA

Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
28
Category
Article
ISSN
0931-7597

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reactions of 1,3diphenyl-2-propenyl acetate (II). Best results are obtained with derivative (Ia). Dimethyl malonate as nucleophile gives the product (IV) with high e.e., whereas benzylamine provides only moderate stereoselectivity. -(JIN, MYUNG-