๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

ChemInform Abstract: Asymmetric Pauson-Khand Cyclization: A Formal Total Synthesis of Natural Brefeldin A.

โœ Scribed by V. BERNARDES; N. KANN; A. RIERA; A. MOYANO; M. A. PERICAS; A. E. GREENE


Book ID
112028777
Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
27
Category
Article
ISSN
0931-7597

No coin nor oath required. For personal study only.


๐Ÿ“œ SIMILAR VOLUMES


ChemInform Abstract: A Formal Synthesis
โœ Y.-G. SUH; J.-K. JUNG; B.-C. SUH; Y.-C. LEE; S.-A. KIM ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 35 KB ๐Ÿ‘ 2 views

A Formal Synthesis of (+)-Brefeldin A. -An advanced synthetic intermediate for (+)-brefeldin A (IX) is efficiently synthesized from Weinreb amide (I). The procedure involves the highly stereoselective construction of the hydroxycyclopentane moiety via an oxabicycloheptanone unit. -(SUH,

ChemInform Abstract: Enantioconvergent F
โœ Pierre Ducray; Bernard Rousseau; Charles Mioskowski ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 32 KB ๐Ÿ‘ 2 views

Enantioconvergent Formal Synthesis of Brefeldin A via Sakai-Catalyzed Cyclization. -A formal total synthesis of the antitumor agent brefeldin A (XII) is presented by asymmetric synthesis of intermediate (XI). Key steps are the asymmetric Sakai cyclization of racemic pentenal (I) and the reductive a