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ChemInform Abstract: A Formal Synthesis of (+)-Brefeldin A.

✍ Scribed by Y.-G. SUH; J.-K. JUNG; B.-C. SUH; Y.-C. LEE; S.-A. KIM

Publisher: John Wiley and Sons
Year: 2010
Weight: 35 KB
Volume: 29
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199843265

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✦ Synopsis

A Formal Synthesis of (+)-Brefeldin A.

-An advanced synthetic intermediate for (+)-brefeldin A (IX) is efficiently synthesized from Weinreb amide (I). The procedure involves the highly stereoselective construction of the hydroxycyclopentane moiety via an oxabicycloheptanone unit. -(SUH,

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