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ChemInform Abstract: Allylation of Aldehydes via Umpolung of π-Allylpalladium(II) with Triethylborane.

✍ Scribed by Masanari Kimura; Iku Kiyama; Tatsuya Tomizawa; Yoshikazu Horino; Shuji Tanaka; Yoshinao Tamaru

Publisher: John Wiley and Sons
Year: 2010
Weight: 39 KB
Volume: 30
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199947089

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## Abstract By using a sterically hindered chiral monodentate spiro phosphite ligand, aromatic or aliphatic aldehydes undergo the title reaction with allylic alcohols as well as allylic donors.