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ChemInform Abstract: Novel Carbonyl-Dependent Regioselective Allylation via Diethylzinc-Mediated Umpolung of π-Allylpalladium.

✍ Scribed by M. KIMURA; Y. OGAWA; M. SHIMIZU; M. SUEISHI; S. TANAKA; Y. TAMARU

Publisher
John Wiley and Sons
Year
2010
Weight
36 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis

Novel Carbonyl-Dependent Regioselective Allylation via Diethylzinc-Mediated Umpolung of π-Allylpalladium.

-The allylation of carbonyl compounds with allyl esters such as (I) in the presence of diethylzinc and catalytic Pd(0) is investigated. With benzaldehyde mainly α-allylation products (III) are obtained, whereas acetone and ethyl acetate yield γ-allylation products (VII) and (IX). -(KIMURA, M.;

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✍ Yoshinao Tamaru 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 29 KB

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