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ChemInform Abstract: Catalytic Asymmetric Allylation of Imines via Chiral Bis-π-allylpalladium Complexes.

✍ Scribed by H. NAKAMURA; K. NAKAMURA; Y. YAMAMOTO


Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
29
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Amphiphilic Catalyt
✍ H. NAKAMURA; J.-G. SHIM; Y. YAMAMOTO 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 31 KB

Amphiphilic Catalytic Allylating Reagent, Bis-π-allylpalladium Complex. -Activated olefins such as (I) and (V) react with intermediary formed bis-π-allylpalladium as the first amphiphilic catalyst at the nucleophilic and electrophilic carbons to produce the double allylation products (IV) and