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ChemInform Abstract: A Synthesis of Theopederin D and a Formal Synthesis of Pederin.

✍ Scribed by Philip J. Kocienski; Robert Narquizian; Piotr Raubo; Christopher Smith; F. Thomas Boyle

Publisher: John Wiley and Sons
Year: 2010
Weight: 32 KB
Volume: 30
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199914277

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✦ Synopsis

A Synthesis of Theopederin D and a Formal Synthesis of Pederin.

-The first synthesis of theopederin D (IV), a cytotoxic metabolite from a marine sponge, based on the coupling of two advanced intermediates (I) and (II) is described. Moreover, an improved synthesis of the amide (VIII), a key intermediate for the preparation of pederin (IX), is reported. -(KOCIENSKI,

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