ChemInform Abstract: A New Platform for Designing Ligands for Asymmetric Induction in Allylic Alkylations.
β Scribed by B. M. TROST; B. BREIT; S. PEUKERT; J. ZAMBRANO; J. W. ZILLER
- Book ID
- 112027827
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 32 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0931-7597
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π SIMILAR VOLUMES
Among several new ligands the (S,S)-BOP ligand affords the best results of regio-and stereoselectivity in the allylic alkylations of 1-and 3-aryl-2-propenyl acetates such as (I) and (V). Alkyl substituted analogues like (VI) react with distinctly lower selectivities in the presence of this ligand. -
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