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ChemInform Abstract: A Modular Approach to Ligands for Asymmetric π-Allyl Palladium Catalyzed Additions.

✍ Scribed by S. R. GILBERTSON; C.-W. T. CHANG

Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
28
Category
Article
ISSN
0931-7597

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✦ Synopsis

A Modular Approach to Ligands for Asymmetric π-Allyl Palladium Catalyzed Additions.

-Among 10 phosphinodihydrooxazoles, prepared by a simple four-step procedure, the ligand RIPOX is the most efficient one. The chirality at the carbon next to the phosphine has little effect on the selectivity of the catalysis, cf. SIPOX.

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