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ChemInform Abstract: [3 + 2] Cycloaddition Reaction of Cyclopropyl Ketones with Alkynes Catalyzed by Nickel/Dimethylaluminum Chloride.

โœ Scribed by Takashi Tamaki; Masato Ohashi; Sensuke Ogoshi


Book ID
112043632
Publisher
John Wiley and Sons
Year
2012
Weight
38 KB
Volume
43
Category
Article
ISSN
0931-7597

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[3+2] Cycloaddition Reaction of Cyclopro
โœ Takashi Tamaki; Dr. Masato Ohashi; Prof. Sensuke Ogoshi ๐Ÿ“‚ Article ๐Ÿ“… 2011 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 328 KB ๐Ÿ‘ 1 views

de reagents. The key to success is the organoaluminum reagents, which activate the carbonyl group of cyclopropyl ketones and stabilize the reaction intermediates. This reaction provides a new method for the synthesis of cyclopentene derivatives. Additional studies to elucidate the reaction mechanism