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[3+2] Cycloaddition Reaction of Cyclopropyl Ketones with Alkynes Catalyzed by Nickel/Dimethylaluminum Chloride

✍ Scribed by Takashi Tamaki; Dr. Masato Ohashi; Prof. Sensuke Ogoshi

Book ID: 101548623
Publisher: John Wiley and Sons
Year: 2011
Tongue: English
Weight: 328 KB
Volume: 123
Category: Article
ISSN: 0044-8249
DOI: 10.1002/ange.201106174

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✦ Synopsis

de reagents. The key to success is the organoaluminum reagents, which activate the carbonyl group of cyclopropyl ketones and stabilize the reaction intermediates. This reaction provides a new method for the synthesis of cyclopentene derivatives. Additional studies to elucidate the reaction mechanism and expand the reaction scope are underway in our laboratory.

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