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ChemInform Abstract: Nickel-Catalyzed Cycloaddition of α,β,γ,δ-Unsaturated Ketones with Alkynes.

✍ Scribed by Hiroaki Horie; Takuya Kurahashi; Seijiro Matsubara

No coin nor oath required. For personal study only.

✦ Synopsis

Bicyclo[3.1.0]hexenes are synthesized with complete diastereoselectivity by cycloaddition of the ketone substrates with symmetrical alkynes.

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Nickel-Catalyzed Cycloaddition of α,β,γ,

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