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ChemInform Abstract: Nickel-Catalyzed Silane Reductions of α,β-Unsaturated Ketones and Nitriles.

✍ Scribed by P. BOUDJOUK; S.-B. CHOI; B. J. HAUCK; A. B. RAJKUMAR

Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
29
Category
Article
ISSN
0931-7597

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ChemInform Abstract: CuH-Catalyzed Enant
ChemInform Abstract: CuH-Catalyzed Enantioselective 1,2-Reductions of α,β-Unsaturated Ketones.
✍ Ralph Moser; Zarko V. Boskovic; Christopher S. Crowe; Bruce H. Lipshutz 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 70 KB 👁 1 views

## Abstract Under optimized conditions, a variety of ketones undergo asymmetric 1,2‐reductions almost exclusively instead of the normally observed 1,4‐reductions in the presence of in situ‐generated CuH which is ligated with an optically active bisphosphane ligand.