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Chemically Triggered C–ON Bond Homolysis of Alkoxyamines. Quaternization of the Alkyl Fragment

✍ Scribed by Brémond, Paul; Koïta, Abdoulaye; Marque, Sylvain R. A.; Pesce, Vincent; Roubaud, Valérie; Siri, Didier

Book ID
115543717
Publisher
American Chemical Society
Year
2011
Tongue
English
Weight
605 KB
Volume
14
Category
Article
ISSN
1523-7060

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Chemically Triggered C–ON Bond Homolysis
Chemically Triggered C–ON Bond Homolysis in Alkoxyamines. Part 2: DFT Investigation and Application of the pH Effect on NMP
✍ Elena Bagryanskaya; Paul Brémond; Mariya Edeleva; Sylvain R. A. Marque; Dmitriy 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 627 KB

## Abstract In recent work, a 15‐fold increase in the C–ON bond homolysis rate constant __k__~d~ of 4‐pyridylethyl‐SG1‐based alkoxyamine was observed upon protonation of the pyridyl moiety in organic solvent. In this report, the pH dependence of __k__~d~ (p__K__~a~ = 4.7) is investigated in D~2~O/C