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Chemically triggered C–ON bond homolysis of alkoxyamines. Part 4: solvent effect

✍ Scribed by Audran, Gérard; Brémond, Paul; Marque, Sylvain R. A.; Obame, Germain


Book ID
115543744
Publisher
The Royal Society of Chemistry
Year
2012
Tongue
English
Weight
422 KB
Volume
3
Category
Article
ISSN
1759-9954

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Chemically Triggered C–ON Bond Homolysis
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## Abstract In recent work, a 15‐fold increase in the C–ON bond homolysis rate constant __k__~d~ of 4‐pyridylethyl‐SG1‐based alkoxyamine was observed upon protonation of the pyridyl moiety in organic solvent. In this report, the pH dependence of __k__~d~ (p__K__~a~ = 4.7) is investigated in D~2~O/C

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