Chemically triggered C–ON bond homolysis of alkoxyamines. Part 4: solvent effect
✍ Scribed by Audran, Gérard; Brémond, Paul; Marque, Sylvain R. A.; Obame, Germain
- Book ID
- 115543744
- Publisher
- The Royal Society of Chemistry
- Year
- 2012
- Tongue
- English
- Weight
- 422 KB
- Volume
- 3
- Category
- Article
- ISSN
- 1759-9954
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## Abstract In recent work, a 15‐fold increase in the C–ON bond homolysis rate constant __k__~d~ of 4‐pyridylethyl‐SG1‐based alkoxyamine was observed upon protonation of the pyridyl moiety in organic solvent. In this report, the pH dependence of __k__~d~ (p__K__~a~ = 4.7) is investigated in D~2~O/C
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