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Chemically Triggered C–ON Bond Homolysis in Alkoxyamines. 6. Effect of the Counteranion

✍ Scribed by Audran, Gérard; Brémond, Paul; Marque, Sylvain R. A.; Obame, Germain

Book ID
120683143
Publisher
American Chemical Society
Year
2013
Tongue
English
Weight
529 KB
Volume
78
Category
Article
ISSN
0022-3263

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📜 SIMILAR VOLUMES

Chemically Triggered C–ON Bond Homolysis
Chemically Triggered C–ON Bond Homolysis in Alkoxyamines. Part 2: DFT Investigation and Application of the pH Effect on NMP
✍ Elena Bagryanskaya; Paul Brémond; Mariya Edeleva; Sylvain R. A. Marque; Dmitriy 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 627 KB

## Abstract In recent work, a 15‐fold increase in the C–ON bond homolysis rate constant __k__~d~ of 4‐pyridylethyl‐SG1‐based alkoxyamine was observed upon protonation of the pyridyl moiety in organic solvent. In this report, the pH dependence of __k__~d~ (p__K__~a~ = 4.7) is investigated in D~2~O/C