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Chemically Triggered C–ON Bond Homolysis of Alkoxyamines. 5. Cybotactic Effect

✍ Scribed by Audran, Gérard; Brémond, Paul; Marque, Sylvain R. A.; Obame, Germain

Book ID: 115517565
Publisher: American Chemical Society
Year: 2012
Tongue: English
Weight: 540 KB
Volume: 77
Category: Article
ISSN: 0022-3263
DOI: 10.1021/jo3016665

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## Abstract In recent work, a 15‐fold increase in the C–ON bond homolysis rate constant __k__~d~ of 4‐pyridylethyl‐SG1‐based alkoxyamine was observed upon protonation of the pyridyl moiety in organic solvent. In this report, the pH dependence of __k__~d~ (p__K__~a~ = 4.7) is investigated in D~2~O/C