Chemically induced dynamic nuclear polarization from the selective recombination of radical pairs in micelles
β Scribed by Hutton, Richard S.; Roth, Heinz D.; Kraeutler, Bernhard; Cherry, William R.; Turro, Nicholas J.
- Book ID
- 127373034
- Publisher
- American Chemical Society
- Year
- 1979
- Tongue
- English
- Weight
- 269 KB
- Volume
- 101
- Category
- Article
- ISSN
- 0002-7863
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## Abstract Geometric isomerizations of olefins following photoinduced electron transfer (PET) are classified according to the relative energetic positions of the radicalβion pairs and the reactant triplets. Each class exhibits characteristic CIDNP (chemically induced dynamic nuclear polarization)
A numerical solution of the stochastic Liouville equation for a microreactor model is applied to the theoretical treatment of time-resolved stimulated nuclear polarization data, obtained during the investigation of micellized radical pairs, conducted in two different modes. Escape rate constants and