✦ LIBER ✦

Investigation of chemical and spin dynamics in micellized radical pairs by time-resolved stimulated nuclear polarization. Theory and experiment

✍ Scribed by A.P. Parnachev; E.G. Bagryanskaya; V.F. Tarasov; N.N. Lukzen; R.Z. Sagdeev

Publisher: Elsevier Science
Year: 1995
Tongue: English
Weight: 529 KB
Volume: 244
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(95)00935-w

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✦ Synopsis

A numerical solution of the stochastic Liouville equation for a microreactor model is applied to the theoretical treatment of time-resolved stimulated nuclear polarization data, obtained during the investigation of micellized radical pairs, conducted in two different modes. Escape rate constants and relaxation parameters of radical pairs formed in the photolysis of methyldeoxybenzoin and benzoin in alkyl sulfate micelles of different sizes have been obtained. The conditions of the S-T 0 quantum oscillations in SNP kinetics have been determined.