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CIDNP [chemically induced dynamic nuclear polarization] evidence for radical pair mechanism in photo-Fries rearrangement

✍ Scribed by Adam, Waldemar; Arce de Sanabia, Josefina


Book ID
126293784
Publisher
American Chemical Society
Year
1973
Tongue
English
Weight
252 KB
Volume
38
Category
Article
ISSN
0022-3263

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## Abstract Geometric isomerizations of olefins following photoinduced electron transfer (PET) are classified according to the relative energetic positions of the radical‐ion pairs and the reactant triplets. Each class exhibits characteristic CIDNP (chemically induced dynamic nuclear polarization)