## Abstract Geometric isomerizations of olefins following photoinduced electron transfer (PET) are classified according to the relative energetic positions of the radicalβion pairs and the reactant triplets. Each class exhibits characteristic CIDNP (chemically induced dynamic nuclear polarization)
Radical pair substitution in chemically induced dynamic nuclear polarization. Co-operative effects
β Scribed by J.A. den Hollander
- Publisher
- Elsevier Science
- Year
- 1975
- Tongue
- English
- Weight
- 961 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0301-0104
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
A numerical solution of the stochastic Liouville equation for a microreactor model is applied to the theoretical treatment of time-resolved stimulated nuclear polarization data, obtained during the investigation of micellized radical pairs, conducted in two different modes. Escape rate constants and
It is found that intersgstem crossings between the singlet and the MS = fl components of the triplet state of radical p&in liquids can produce nuclear and electron spin polarizations when two radicals diffuse apart follOWing arl initial encounter and subsequently undergo a second nonreactive encount