## Abstract An interesting and topical question in modern inorganic chemistry is: To what extent are the well‐known chemistry of dispersed metals and the new technique of chemical synthesis with free metal atoms interrelated? Or in other words: Where, do these two facets of metal chemistry meet? In
Chemical Syntheses with Metal Atoms: Preparation of Bis(butadiene)iron Complexes and Butadienetetracarbonlychromium
✍ Scribed by Dr. Ernst Koerner von Gustorf; Ottmar Jaenicke; Prof. Dr. Oskar E. Polansky
- Publisher
- John Wiley and Sons
- Year
- 1972
- Tongue
- English
- Weight
- 237 KB
- Volume
- 11
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
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Salene-Fe III complexes of the types LFeCl and [LFe(CN) 2 ] - Fe(salene)-NC-M species. Cyclic voltammetry showed that there are significant electronic interactions between the two were treated with organometallic reagents to introduce the cyanide-linked units (CO) 5 Cr, (CO) 5 Mo, (CO) 5 W, Cp(CO) 2
Gradual decomposition occurs above the temperature stated. b, Recorded in CHCI, solution. ') Recorded in a nujol mull; shoulders at 2190 and 2100 are also observed. d, Recorded in a nulol mull.
## Abstract The preparation of the ditertiary phosphines 2,11‐bis (di‐__m__‐tolylphosphinomethyl)benzo [__c__]phenanthrene (**1b**), 2,11‐bis (di‐__p__‐anisylphosphinomethyl)benzo‐[__c__]phenanthrene (**1c**), 2,11‐bis (di‐__m__‐trifluoromethylphenylphosphinomethyl) benzo‐[__c__]phenanthrene (**1d*
## Abstract Reaction of a twofold molar excess of bis(2‐pyridylmethyl)amine DPA with 8α‐bromoAc4riboflavin in dry DMF over 24 h affords the 8α‐[bis(2‐pyridylmethyl)amine]‐__N__‐Ac~4~riboflavin ligand. This compound can be described as a tweezer in which the flavin moiety acts as a potential electro