The ligand 2,1 l-bis(diphenylphosphinomethyl)benzo[c]phenanthrene (1) has been used to prepare complexes of the type [PtL(l)] (L = C,H,, CH,=CH-CO,Me, PhC-CPh, MeC-CMe, MeO,CC=CCO,Me, (i-Pr)O,CC-CCO,(i-Pr), Ph,P and CO). It is shown that these complexes are less labile than the corresponding species
Transition metal complexes with bidentate ligands spanning trans-positions. IV. Preparation and properties of some rhodium and iridium complexes of 2,11-bis(diphenylphosphinomethyl)benzo [c]phenanthrene
✍ Scribed by Frank J. S. Reed; Luigi M. Venanzi
- Publisher
- John Wiley and Sons
- Year
- 1977
- Tongue
- German
- Weight
- 787 KB
- Volume
- 60
- Category
- Article
- ISSN
- 0018-019X
No coin nor oath required. For personal study only.
✦ Synopsis
Gradual decomposition occurs above the temperature stated. b, Recorded in CHCI, solution.
') Recorded in a nujol mull; shoulders at 2190 and 2100 are also observed. d, Recorded in a nulol mull.
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