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Transition Metal Complexes with Bidentate Ligands Spanning trans-Positions. VII. The preparation of the five-coordinate complexes [M(CO)3(1)] (M = Fe, Ru; (1) = 2,11-bis(diphenylphosphinomethyl)benzo[c]phenanthrene)

✍ Scribed by Rolf Holderegger; Luigi M. Venanzi

Publisher
John Wiley and Sons
Year
1979
Tongue
German
Weight
292 KB
Volume
62
Category
Article
ISSN
0018-019X

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✦ Synopsis

Abstract

The five‐coordinate mononuclear complexes [M(CO)~3~(1)] (M = Fe, Ru; (1) = 2,11‐bis(diphenylphosphinomethyl)benzo[c]phenanthrene) have been prepared and assigned trigonal bipyramidal structures with apical phosphorus atoms from IR. and NMR. data.

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