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Chain transfer during the aqueous ring-opening metathesis polymerization of 7-oxanorbornene derivatives

✍ Scribed by France, Marcia B.; Grubbs, Robert H.; McGrath, Dominic V.; Paciello, Rocco A.

Book ID
127270990
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
775 KB
Volume
26
Category
Article
ISSN
0024-9297

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πŸ“œ SIMILAR VOLUMES

Aqueous ring-opening metathesis polymeri
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## Abstract A number of 7‐oxanorbornene derivatives with hydroxymethyl, methoxymethyl and acetoxymethyl functionalities were synthesised and investigated as monomers in ring‐opening metathesis polymerisation (ROMP) catalysed by commercial ruthenium trichloride in aqueous ethanolic solvents. Compari

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## Abstract 2,3‐Bis(methoxymethyl)‐7‐oxanorbornene was polymerised in water plus at least 9gdm^βˆ’3^ Synperonic F127 by ring‐opening metathesis polymerisation (ROMP) initiated by commercial ruthenium trichloride. Stable dispersions with particle radii 0.03 ΞΌn or less were formed. Polymer molecular we