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Aqueous ring-opening metathesis polymerisation of 7-oxanorbornene derivatives with oxygen-containing functionalities

✍ Scribed by Shui-Yu Lu; Judith M. Amass; Nazia Majid; Dermott Glennon; Andrew Byerley; Frank Heatley; Peter Quayle; Colin Booth; Stephen G. Yeates; John C. Padget

Publisher
John Wiley and Sons
Year
1994
Tongue
English
Weight
671 KB
Volume
195
Category
Article
ISSN
1022-1352

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✦ Synopsis

Abstract

A number of 7‐oxanorbornene derivatives with hydroxymethyl, methoxymethyl and acetoxymethyl functionalities were synthesised and investigated as monomers in ring‐opening metathesis polymerisation (ROMP) catalysed by commercial ruthenium trichloride in aqueous ethanolic solvents. Comparison was made with related polymerisations of 7‐oxanorbornene derivatives with anhydride, methoxymethyl and carboxylic acid functionalities. The structures of the polymers were investigated by ^1^H and ^13^C NMR and their molar masses and molar mass distributions by gel‐permeation chromatography.

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