Aqueous ring-opening metathesis polymerization of carboximide-functionalized 7-oxanorbornenes
β Scribed by Hillmyer, Marc A.; Lepetit, Christine; McGrath, Dominic V.; Novak, Bruce M.; Grubbs, Robert H.
- Book ID
- 127111566
- Publisher
- American Chemical Society
- Year
- 1992
- Tongue
- English
- Weight
- 755 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0024-9297
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π SIMILAR VOLUMES
## Abstract A number of 7βoxanorbornene derivatives with hydroxymethyl, methoxymethyl and acetoxymethyl functionalities were synthesised and investigated as monomers in ringβopening metathesis polymerisation (ROMP) catalysed by commercial ruthenium trichloride in aqueous ethanolic solvents. Compari
## Abstract 2,3βBis(methoxymethyl)β7βoxanorbornene was polymerised in water plus at least 9gdm^β3^ Synperonic F127 by ringβopening metathesis polymerisation (ROMP) initiated by commercial ruthenium trichloride. Stable dispersions with particle radii 0.03 ΞΌn or less were formed. Polymer molecular we
Ring-opened metathesis polymers of 7-phenylnorbornadiene and benzonorbornadiene have been prepared using a variety of catalysts based on Ru, Os, Ir, W and Mo chloride salts and complexes. Detailed "C and 'H NMR spectra of these materials and their corresponding hydrogenated derivatives have been obt