The photosensitized polymerization of styrene in bulk was investigated in the temperature range of 25-70Β°C with respect to the average rate coefficient of bimolecular chain termination k t , especially its chain length dependence at low conversions, by means of pulsed laser polymerization (PLP). Thr
β¦ LIBER β¦
Chain Length Dependent Propagation Rate Coefficient k p in Pulsed-Laser Polymerization: Variation with Temperature in the Bulk Polymerization of Styrene and Methyl Methacrylate
β Scribed by Olaj, Oskar Friedrich; Vana, Philipp; Zoder, Monika
- Book ID
- 125538278
- Publisher
- American Chemical Society
- Year
- 2002
- Tongue
- English
- Weight
- 89 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0024-9297
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## Abstract The propagation rate coefficient __K__~p~ of the freeβradical bulk polymerization of styrene is determined between 30 and 90Β°C up to a maximum pressure of 2800 bar. The data from pulsedlaser polymerizations and product analyses by gelβpermeation chromatography (PLPβGPC) are adequately r
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