✦ LIBER ✦

Variation of the propagation rate coefficient with pressure and temperature in the free-radical bulk polymerization of styrene

✍ Scribed by Michael Buback; Frank-Dieter Kuchta

Publisher: John Wiley and Sons
Year: 1995
Tongue: English
Weight: 530 KB
Volume: 196
Category: Article
ISSN: 1022-1352
DOI: 10.1002/macp.1995.021960608

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✦ Synopsis

Abstract

The propagation rate coefficient K~p~ of the free‐radical bulk polymerization of styrene is determined between 30 and 90°C up to a maximum pressure of 2800 bar. The data from pulsedlaser polymerizations and product analyses by gel‐permeation chromatography (PLP‐GPC) are adequately represented by the expression:

The conseaquences of deducing activation volumes and activation energies from k~p~/(L · mol^−1^ · s^−1^) or from__k__*~p~/(kg · mol^‐1^ ·. S^−1^) are outlined.

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