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Pressure dependence of propagation rate coefficients in free-radical homopolymerizations of methyl acrylate and dodecyl acrylate

✍ Scribed by Michael Buback; Caroline H. Kurz; Claudia Schmaltz


Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
680 KB
Volume
199
Category
Article
ISSN
1022-1352

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## Abstract In acrylate polymerizations both SPRs and tertiary MCRs occur. Via pulsed laser polymerization, using a wide range of LPRRs, in conjunction with aqueous‐phase size‐exclusion chromatography, the polymerization of 1.35 mol · L^βˆ’1^ acrylic acid in aqueous solution has been investigated at