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Termination Kinetics of Methyl Acrylate and Dodecyl Acrylate Free-Radical Homopolymerizations up to High Pressure

✍ Scribed by Michael Buback; Albrecht Kuelpmann; Caroline Kurz


Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
207 KB
Volume
203
Category
Article
ISSN
1022-1352

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✦ Synopsis


Pressure dependence of the termination rate coefficient, k t , in the initial period ("plateau region") of methyl acrylate (MA) and dodecyl acrylate (DA) free-radical bulk homopolymerizations at 40 8C. The filled symbols are from ref. [23]


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Termination rate coefficients, k t , for the terpolymerization of mixtures containing the three acrylates: methyl, butyl, and dodecyl acrylate or the corresponding members of the methacrylate family: methyl, butyl, and dodecyl methacrylate, have been measured via the single pulse (SP)-PLP technique.