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Chain Length Dependent Termination in Pulsed-Laser Polymerization. 9. The Influence of Solvent on the Rate Coefficient of Bimolecular Termination in the Polymerization of Styrene

✍ Scribed by Olaj, Oskar Friedrich; Zoder, Monika; Vana, Philipp

Book ID
126021869
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
68 KB
Volume
34
Category
Article
ISSN
0024-9297

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Chain length-dependent termination in pu
Chain length-dependent termination in pulsed-laser polymerization. VIII. The temperature dependence of the rate coefficient of bimolecular termination in the bulk polymerization of styrene
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The photosensitized polymerization of styrene in bulk was investigated in the temperature range of 25-70Β°C with respect to the average rate coefficient of bimolecular chain termination k t , especially its chain length dependence at low conversions, by means of pulsed laser polymerization (PLP). Thr

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Chain-length dependent termination in pulsed-laser polymerization, 3. On the prospects of determining the bimolecular termination constant kt from rate data
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The correct (event-weighted) average of k,, (k,), has been calculated from simulation data for pseudostationary laser-induced polymerization for a kinetic scheme with chain-length dependent termination and compared to the average k, which is obtained by employing the formal procedures, originally de

Chain-length dependent termination in pu
Chain-length dependent termination in pulsed-laser polymerization, 2. On the prospects of determining the bimolecular termination constant kt from the second moment of the chain-length distribution
✍ Oskar Friedrich Olaj; Andreas Kornherr; Gerhard Zifferer πŸ“‚ Article πŸ“… 1997 πŸ› John Wiley and Sons 🌐 English βš– 528 KB

## Abstract The correct (event weighted) average of __k__~t~, γ€ˆ__k__~t~〉, has been calculated for pseudostationary laser‐induced polymerization for a kinetic scheme with chain‐length dependent termination and compared to the average __kΜ„__~t~ obtained by formally solving for __k__~t~ the expression