๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

Chain-length dependent termination in pulsed-laser polymerization, 4. The influence of the type of mean involved in the bimolecular termination step

โœ Scribed by Oskar Friedrich Olaj; Andreas Kornherr; Gerhard Zifferer

Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
698 KB
Volume
7
Category
Article
ISSN
1022-1344

No coin nor oath required. For personal study only.

๐Ÿ“œ SIMILAR VOLUMES

Chain length-dependent termination in pu
Chain length-dependent termination in pulsed-laser polymerization. VIII. The temperature dependence of the rate coefficient of bimolecular termination in the bulk polymerization of styrene
โœ Oskar Friedrich Olaj; Philipp Vana ๐Ÿ“‚ Article ๐Ÿ“… 2000 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 157 KB ๐Ÿ‘ 3 views

The photosensitized polymerization of styrene in bulk was investigated in the temperature range of 25-70ยฐC with respect to the average rate coefficient of bimolecular chain termination k t , especially its chain length dependence at low conversions, by means of pulsed laser polymerization (PLP). Thr

Chain-length dependent termination in pu
Chain-length dependent termination in pulsed-laser polymerization, 3. On the prospects of determining the bimolecular termination constant kt from rate data
โœ Oskar Friedrich Olaj; Andreas Kornherr; Gerhard Zifferer ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 613 KB

The correct (event-weighted) average of k,, (k,), has been calculated from simulation data for pseudostationary laser-induced polymerization for a kinetic scheme with chain-length dependent termination and compared to the average k, which is obtained by employing the formal procedures, originally de

The influence of the Poissonian characte
The influence of the Poissonian character of chain growth on propagation probabilities in free radical polymerization with chain-length dependent termination
โœ Oskar Friedrich Olaj; Gerhard Zifferer; Andreas Kornherr ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 457 KB ๐Ÿ‘ 3 views

It is shown that the (established) method of deriving chain-length distributions from propagation probabilities is not fully consistent with the Poissonian character of chain propagation if termination is chain-length dependent: the fluctuation of chain propagation leads to somewhat lower radical co