Chain-length dependent termination in rotating sector polymerization, 1. The evaluation of the rate constant of chain propagation kp
โ Scribed by Oskar Friedrich Olaj; Andreas Kornherr; Gerhard Zifferer
- Publisher
- John Wiley and Sons
- Year
- 1999
- Tongue
- English
- Weight
- 113 KB
- Volume
- 8
- Category
- Article
- ISSN
- 1022-1344
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
It is shown that the (established) method of deriving chain-length distributions from propagation probabilities is not fully consistent with the Poissonian character of chain propagation if termination is chain-length dependent: the fluctuation of chain propagation leads to somewhat lower radical co
The photosensitized polymerization of styrene in bulk was investigated in the temperature range of 25-70ยฐC with respect to the average rate coefficient of bimolecular chain termination k t , especially its chain length dependence at low conversions, by means of pulsed laser polymerization (PLP). Thr