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Is the rate constant of chain propagation kp in radical polymerization really chain-length independent?

โœ Scribed by Oskar Friedrich Olaj; Philipp Vana; Monika Zoder; Andreas Kornherr; Gerhard Zifferer


Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
113 KB
Volume
21
Category
Article
ISSN
1022-1336

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The influence of the Poissonian characte
โœ Oskar Friedrich Olaj; Gerhard Zifferer; Andreas Kornherr ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 457 KB ๐Ÿ‘ 1 views

It is shown that the (established) method of deriving chain-length distributions from propagation probabilities is not fully consistent with the Poissonian character of chain propagation if termination is chain-length dependent: the fluctuation of chain propagation leads to somewhat lower radical co