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(CF3)2Cd and (CF3)2Zn: Spectral properties and chemical behaviour

✍ Scribed by H. Lange; D. Naumann

Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
24 KB
Volume
29
Category
Article
ISSN
0022-1139

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✍ S. V. Pasenok; N. V. Kirij; Yu. L. Yagupolskii; D. Naumann; W. Tyrra; A. Fitzner πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 German βš– 93 KB πŸ‘ 1 views

The reactions of Zn(CF 3 )Br Β΄2 CH 3 CN, Cd(CF 3 ) 2 Β΄2 CH 3 CN or Bi(CF 3 ) 3 /AlCl 3 with tertiary amines lead to the formation of quaternary ammonium salts of the general formula [R 3 NCF 2 H]X. The reaction of 4-N,N-dimethylaminopyridine with Zn(CF 3 )Br Β΄2 CH 3 CN yields (Ndifluoromethyl)-4-N,N