The rate constants for the reactions of OH radicals with CH 3 OCF 2 CF 3 , CH 3 OCF 2 CF 2 CF 3 , and CH 3 OCF(CF 3 ) 2 have been measured over the temperature range 250-430 K. Kinetic measurements have been carried out using the flash photolysis, laser photolysis, and discharge flow methods combine
Vapor pressures, liquid molar volumes, vapor non-ideality, and critical properties of CF3OCF2CF2CF3, c-CF2CF2CF2CF2O, CF3OCF2OCF3, and CF3OCF2CF2H
✍ Scribed by M. Salvi-Narkhede; James L. Adcock; Andrei Gakh; W.Alexander Van Hook
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 107 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0021-9614
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract Smog chamber/FTIR techniques were used to measure __k__(Cl + HCF~2~OCF~2~OCF~2~‐CF~2~OCF~2~H) = __k__(Cl + HCF~2~O(CF~2~O)~__n__~(CF~2~CF~2~O)~__m__~CF~2~H) = (5.0 ± 1.4) × 10^−17^ cm^3^ molecule^−1^ s^−1^ in 700 Torr of N~2~/O~2~ diluent at 296 ± 1 K. The Cl‐initiated atmospheric oxida
Rate constant ratios, k d /k c , for the disproportionation/combination reaction at a temperature of 295 Ϯ 2 K, have been measured as 0.034 Ϯ 0.009 for the collision between CF 3 CH 2 CF 2 ϩ CF 3 radicals and as 0.075 Ϯ 0.019 for CF 3 CH 2 CF 2 ϩ CF 3 CH 2 CF 2 radicals. The effect of the two fluori
## Abstract The intermolecular interaction energy curves of CH~3~OCH~3~CH~2~F~2~, CF~3~OCH~3~CH~2~F~2~, CF~3~OCF~3~CH~2~F~2~, CH~3~OCH~3~CHF~3~, CF~3~OCH~3~CHF~3~, and CF~3~OCF~3~CHF~3~ complexes were calculated by the MP2 level __ab initio__ molecular orbital method using the 6‐311G\*\* basi
## Abstract The relative rate technique has been used to determine the rate constants of the reactions of OH radicals with CF~3~CClCCl~2~ (__k__~1~), CF~3~CClCClCF~3~ (__k__~2~) and CF~3~CFCFCF~3~ (__k__~3~). Experiments were carried out at (298±2) K and atmospheric pressure using ultrapure nitr