✦ LIBER ✦

SF5CFCF2 and CF3CFCF2 in phosphorus chemistry: a comparison

✍ Scribed by A. Gentzrsch; H. Wessolowski; G.-V. Röschenthaler

Publisher: Elsevier Science
Year: 1991
Tongue: English
Weight: 35 KB
Volume: 54
Category: Article
ISSN: 0022-1139
DOI: 10.1016/s0022-1139(00)83566-6

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

The molecular structure of bis(pentafluo

The molecular structure of bis(pentafluorosulfur)methane (SF5)2CH2 and perfluorovinylsulfur pentafluoride SF5CFCF2

✍ Ilse Weiss; Heinz Oberhammer; Gary L. Gard; Rolf Winter; Konrad Seppelt 📂 Article 📅 1992 🏛 Elsevier Science 🌐 English ⚖ 518 KB

Synthesis, and spectral and X-ray struct

Synthesis, and spectral and X-ray structural studies of a novel delocalised triphosphazene (CF3)2PNP(CF3) 2NPPh3 and the triosmium cluster complex Os3(CO)11[(CF3)2PNP(CF3)2NPPh3]

✍ H.G. Ang; Y.M. Cai; W.L. Kwik 📂 Article 📅 1993 🏛 Elsevier Science 🌐 English ⚖ 530 KB

Reactions of CF3SF3NCF3 with nucleophil

Reactions of CF3SF3NCF3 with nucleophiles and the preparation of CF3SF4N(F)Rf (Rf = CF3,C2F5)

✍ Shin-Liang Yu; Jean'ne M. Shreeve 📂 Article 📅 1976 🏛 Elsevier Science 🌐 English ⚖ 464 KB

The new compounds, CF3SF(0)=NCF3 and CF3SF(=NCH3)=NCF3, result from nucleophilic displacement reactions of CF3SF3=NCF3 with water and methylamine, respectively. Higher yields of the di-imine are obtained when CH3N(Si(CH3)3)2 is substituted for CH3NH2. Stable fluoroamines, CF3SF4N(F)Rf (Rf = CF3, C2F

Vapor pressures, liquid molar volumes, v

Vapor pressures, liquid molar volumes, vapor non-ideality, and critical properties of CF3OCF2CF2CF3, c-CF2CF2CF2CF2O, CF3OCF2OCF3, and CF3OCF2CF2H

✍ M. Salvi-Narkhede; James L. Adcock; Andrei Gakh; W.Alexander Van Hook 📂 Article 📅 1993 🏛 Elsevier Science 🌐 English ⚖ 107 KB

A new cyclic fluorinated trisulfone (CF2

A new cyclic fluorinated trisulfone (CF2SO2)3 and fluorinated derivatives: SO2(CF2SO2F)2, CF2(SO2CF3)2, CF3SO2CF2SO2F, CF2(SO2F)2 and CF3SO2CF2SO2CF2SO2F

✍ Alfred Waterfeld; Ilse Weiss; Heinz Oberhammer; Gary L. Gard; Rudiger Mews 📂 Article 📅 1994 🏛 Elsevier Science 🌐 English ⚖ 485 KB

Substituent effects on the disproportion

Substituent effects on the disproportionation-combination rate constant ratios for gas-phase halocarbon radicals. IV. Reactions of ·CF3 + CF3CH2CF2· and CF3CH2CF2· + CF3CH2CF2·

✍ Shane R. Smith; Bert E. Holmes 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 161 KB 👁 2 views

Rate constant ratios, k d /k c , for the disproportionation/combination reaction at a temperature of 295 Ϯ 2 K, have been measured as 0.034 Ϯ 0.009 for the collision between CF 3 CH 2 CF 2 ϩ CF 3 radicals and as 0.075 Ϯ 0.019 for CF 3 CH 2 CF 2 ϩ CF 3 CH 2 CF 2 radicals. The effect of the two fluori