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Cationic Polymerization of Dienes. 5. † Study of the Polymerization of 1,3-Pentadiene cis / trans Isomers and Evidences of the Origins of the Insoluble Fraction

✍ Scribed by Delfour, Marilyn; Bennevault-Celton, Véronique; Cheradame, Hervé; Mercier, Florence; Barré, Nicole

Book ID
125330712
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
342 KB
Volume
36
Category
Article
ISSN
0024-9297

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Cyclic oligomers in the cationic polymer
Cyclic oligomers in the cationic polymerization of cis- and trans-2,3-dimethylthiirane
✍ Wilfried M. Van Craeynest; Eric J. Goethals 📂 Article 📅 1976 🏛 Elsevier Science 🌐 English ⚖ 452 KB

Under the influence of triethyloxonium tetrafluoroborate in methylene chloride, cis-and trans-2,3-dimethylthiirane are transformed to their corresponding polymers almost instantaneously (at temperatures between 0 and 20 °) but within a few hours these polymers completely degrade to form a mixture of