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The cationic polymerization of CIS, CIS cycloocta-1,3-diene

✍ Scribed by M.A.S. Mondal; R.N. Young


Publisher
Elsevier Science
Year
1971
Tongue
English
Weight
832 KB
Volume
7
Category
Article
ISSN
0014-3057

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## Abstract The thermal reaction of 1,3‐butadiene (BD) has been studied between 464 and 557Β°K at pressures between 49 and 450 torr. The products are 4‐vinylcyclohexene (VCH) and __cis__, __cis__‐cycloocta‐1,5‐diene (COD), and their formations are second order. The rate constant (in 1/mol Β· sec) for

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The recent communication by Shani (1) in which the photolysis of cis, cis-cyclodeca---3,8-diene-1, 6-dione (I) is reported to give cis,\*, cis-tricyclo[5. 3. 0. 0 2, (+d ecane-4,9--dione prompts us to report results we had obtained independently which lead to the cis, -anti, cis (IIa) stereochemical