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Cationic polymerization of 1,3-pentadiene in the presence of arenes

โœ Scribed by Peng Yu-Xing; Liu Jia-Lin; Cun Lin-Feng; Dai Han-Song


Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
283 KB
Volume
14
Category
Article
ISSN
0256-7660

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Cationic Copolymerization of 1,3-Pentadi
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The cationic copolymerization of 1,3-pentadiene (PD) with isoprene (IP) initiated by AICl, was carried out in toluene. The microstructure of the copolymer chain was characterized by IR and 'H NMR. IP is incorporated in the copolymer chain mainly in cyclic segments. The PD-IP copolymer has a much hig

Cationic copolymerization of 1,3-pentadi
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Copolymerizations of 1,3-pentadiene (PD) with 1,3-cyclopentadiene (CPD) initiated by aluminium trichloride were carried out in toluene. The addition of CPD in the PD polymerization system does not affect the molecular weight but greatly increases the softening point of the polymer due to the introdu