𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Chemoselective mechanism of (Z)-1,3-pentadiene polymerization in the presence of cyclopentadienyltitanium trichloride and methylaluminoxane

✍ Scribed by Pasquale Longo; Gaetano Guerra; Fabia Grisi; Sante Pizzuti; Adolfo Zambelli


Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
404 KB
Volume
199
Category
Article
ISSN
1022-1352

No coin nor oath required. For personal study only.


πŸ“œ SIMILAR VOLUMES


Copolymerization of styrene with (Z)-1,3
✍ Pasquale Longo; Antonio Proto; Patrizia Oliva; Irene Sessa; Adolfo Zambelli πŸ“‚ Article πŸ“… 1997 πŸ› John Wiley and Sons 🌐 English βš– 123 KB πŸ‘ 1 views

Copolymerization of styrene with (Z )-1,3-pentadiene affords copolymers mostly containing 1,2 pentadiene units. Both the styrene and the pentadiene units are in syndiotactic arrangement but the comonomer sequence distribution is far from bernoullian. Interestingly, the behavior of (Z )-1,3-pentadien

Kinetics and reaction mechanism of templ
✍ Rainaldi, Iacopo; Cristallini, Caterina; Ciardelli, Gianluca; Giusti, Paolo πŸ“‚ Article πŸ“… 2000 πŸ› John Wiley and Sons 🌐 English βš– 164 KB πŸ‘ 1 views

Conductimetry was used for monitoring the radical polymerization of a weak electrolyte (acrylic acid) in aqueous solution and for determination of the kinetic parameters of the reaction (reaction order with respect to monomer, activation energy). The results obtained were consistent with those deter

The kinetics and mechanism of the reacti
✍ Jan Chlebicki; Larisa Yu. Shiman; Andrey K. Guskov; Mikhail G. Makarov; Valerij πŸ“‚ Article πŸ“… 1997 πŸ› John Wiley and Sons 🌐 English βš– 133 KB πŸ‘ 1 views

Rate constants for the reaction of 1-chloro-2,3-epoxypropane with p-cresol in the presence of basic catalysts were studied at the temperature range of 71 -100Β°C. It was found that in the presence of sodium p-cresolate, three consecutive reactions proceeded giving the following products: 1-chloro-3-

Activation of iPr(CpFluo)ZrCl2 by methyl
✍ DorothΓ©e Coevoet; Henri Cramail; Alain Deffieux πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 English βš– 93 KB

The homopolymerization of hex-1-ene in presence of the iPr(CpFluo)ZrCl 2 /MAO system has been investigated in solvents of various polarity and coordinating power (toluene, methylene dichloride and o-dichlorobenzene). Polymerization kinetics were monitored by dilatometry. A strong enhancement of the

Stopped-flow polymerizations of ethene a
✍ Vincenzo Busico; Roberta Cipullo; Valentina Esposito πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 English βš– 78 KB πŸ‘ 1 views

The kinetics of ethene and propene polymerization at 20 -60 8C in the presence of the homogeneous catalyst system rac-Me 2 Si(2-methyl-4-phenyl-1-indenyl) 2 ZrCl 2 /methylaluminoxane was investigated by means of stopped-flow techniques. The specific rate of chain propagation, measured at the very sh