Living polymerization of 1,3-butadiene with the catalyst system composed of cyclopentadienyltitanium trichloride and methylaluminoxane
โ Scribed by Akira Miyazawa; Toshio Kase; Kazuo Soga
- Publisher
- John Wiley and Sons
- Year
- 1999
- Tongue
- English
- Weight
- 101 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0887-624X
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๐ SIMILAR VOLUMES
The block copolymerization of allene derivatives (3A-3D) with 1,3-butadiene (2) by [(allyl)NiOCOCF 3 ] 2 (1) is described. For instance, the living coordination polymerization of phenylallene (3A, 50 equiv) starting from the living poly(2), which was prepared by the polymerization of 2 (160 equiv) b
The kinetics of ethene and propene polymerization at 20 -60 8C in the presence of the homogeneous catalyst system rac-Me 2 Si(2-methyl-4-phenyl-1-indenyl) 2 ZrCl 2 /methylaluminoxane was investigated by means of stopped-flow techniques. The specific rate of chain propagation, measured at the very sh