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cis-Specific Living Polymerization of 1,3-Butadiene with CoCl2 and Methylaluminoxane

โœ Scribed by Dilip Chandra Deb Nath; Takeshi Shiono; Tomiki Ikeda

Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
196 KB
Volume
203
Category
Article
ISSN
1022-1352

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Investigation of methylaluminoxane as a
Investigation of methylaluminoxane as a cocatalyst for the polymerization of 1,3-butadiene to high cis-1,4-polybutadiene
โœ Peter Cass; Kerry Pratt; Terry Mann; Bob Laslett; Ezio Rizzardo; Robert Burford ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 191 KB ๐Ÿ‘ 1 views

The catalytic system Co/methylaluminoxane/tert-butyl chloride has been studied and optimized for the polymerization of 1,3-butadiene to high cis-1,4-polybutadiene. The ratio of the individual catalyst components was investigated to achieve maximum conversion, stereoregularity, and molecular weight.