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Cationic polymerization of 1,3-pentadiene initiated with aluminium chloride in non-polar solvent: study of the initiation mechanism

✍ Scribed by Fabienne Duchemin; Véronique Bennevault-Celton; Hervé Chéradame; Anne Macedo

Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
643 KB
Volume
199
Category
Article
ISSN
1022-1352

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Demonstration of the Existence of Long-L
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## Abstract **Summary:** A kinetic study of the polymerization of a mixture of 1,3‐pentadiene isomers initiated by AlCl~3~ was carried out in pentane at −10 and 20 °C. A second apparent monomer order was found mainly at room temperature and was explained by a complexation of propagating active cent

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## Abstract Summary: The cationic polymerization of 1,3‐pentadiene initiated by AlCl~3~ was studied in nonpolar solvent. It was previously shown that at room temperature the active species were long‐lived and that the number‐average molar mass of the polymer chains was increasing with the polymeriz

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Cationic polymerization of isobutylene initiated by Friedel-Crafts catalysts. Peculiarities of the initiation reaction in a non-polar medium
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The effect of water on the cationic polymerization of isohutylene by AIEtCI, in n-heptane has been studied. The condition of complete polymerization inhibition is attained a t [H,O] 5 mol/l. Slow polymerization with an induction period is detected a t [H,O]/[AIEtCI,] 5 1. By means of 2,6-DTBP and 0,